Оn the issue of creating composite ceramic materials
DOI:
https://doi.org/10.33216/1998-7927-2025-290-4-57-62Keywords:
composite ceramics, two-layer tile, silicon carbide, strontium titanate, semi-dry pressing, water absorption and porosity, apparent density and flexural strengthAbstract
Due to the intensive development of modern wireless communication technologies, and the continuous increase in the number of electronic devices operating across a wide frequency range, there is a steady rise in artificial electromagnetic radiation in the surrounding environment. This leads to a gradual increase in the electromagnetic background, which creates potential risks for the uninterrupted and reliable operation of highly sensitive electronic equipment, and may also have a negative impact on the health and overall condition of biological objects, including humans. Therefore, research aimed at creating new effective materials with high electromagnetic shielding properties, which should also exhibit satisfactory operational characteristics, becomes particularly relevant. This work presents the results of an experimental study on the development of a composite ceramic tile containing electrically conductive and ferroelectric functional components. Silicon carbide was used as the electrically conductive additive at 30 wt.%, while strontium titanate, a ferroelectric additive, was introduced in amounts of 10, 20, and 30 wt.%. The experimental tile has a two-layer structure: the first layer consists of a ceramic mass with 30 wt.% silicon carbide, and the second layer is a ceramic mass with the corresponding content of strontium titanate. The samples were formed by the semi-dry pressing method and fired in a silicate furnace at temperatures of 1120–1140 °C with an isothermal holding time of 20 minutes. The study analyzed the influence of varying strontium titanate content on the physical and mechanical properties of the samples. Key operational properties such as water absorption, porosity, apparent density, and flexural strength were determined. The optimal composite ceramic composition was identified, providing a balanced combination of performance characteristics: water absorption – 6.84%, porosity – 14.90%, apparent density – 2.16 g/cm³, and flexural strength – 26.5 MPa. It was established that an increase in apparent density can serve as an indicator of enhanced overall density and potential strength of the material, despite some increase in porosity. The results of this study can be used in further development of ceramic materials with functional properties suitable for applications under electromagnetic radiation exposure.
References
1. Sahu M., Behera S., Chattopadhyay B. The Influence of Electromagnetic Field Pollution on Human Health: A Systematic Review. Siriraj Medical Journal, 2021. 73(7), 485–492. https://doi.org/10.33192/Smj.2021.63
2. Green M., X. Chen Recent progress of nanomaterials for microwave absorption. Journal of Materiomics, 2019. 5(4), 503-541. https://doi.org/10.1016/j.jmat.2019.07.003
3. Dahl M., Liu Y., Yin Y. Composite Titanium Dioxide Nanomaterials. Chemical Reviews, 2014. 114(19), 9853-9889. https://doi.org/10.1021/cr400634p
4. Vovchenko L., Lozitsky O., Matzui L., Oliynyk V., Zagorodnii V., Skoryk M. Electromagnetic shielding properties of epoxy composites with hybrid filler nanocarbon/BaTiO3. Materials Chemistry and Physics, 2020. 240(15), 122234. https://doi.org/10.1016/j.matchemphys.2019.122234
5. Joseph N., Singh S.K., Sirugudu R.K., Murthy V.R.K., Ananthakumar S., Sebastian M. T. Effect of silver incorporation into PVDF-barium titanate composites for EMI shielding applications. Materials Research Bulletin, 2013. 48(4), 1681-1687. https://doi.org/10.1016/j.materresbull.2012.11.115
6. Matzui L.Yu., Vovchenko L.L., Yakovenko O.S., Turkov O.V., Zhuravkov O.V., Ischenko O.V., Diyuk V.E., Dyachenko A.G., Pryhunova O.V., Zagorodnii V.V., Cojocari M., Fedorov G., Kuzhir P. Microwave properties of composites based on glass microsphers coated with ferromagnetic compounds. Journal of Materials Research and Technology, 2025. 36, 7043-7054. https://doi.org/10.1016/j.jmrt.2025.04.283
7. Navdeep S., Gagan D. Carbon Nanotubes based Composites for Electromagnetic Absorption - A Review. Current Applied Materials, 2022. 1(1), 18 10.2174/2666731201666210803110914
8. Hryhoruk V.I., Oliynyk V.V., Zagorodniy V.V., Lisachuk G.V., Kryvobok R.V., Voloshchuk V.V., Maystat M.S., Lapuzina O.M. Study of the electrodynamic properties of composite ceramics. Himia, Fizika ta Tehnologia Poverhni, 2023. 14(2), 249–254 https://doi.org/10.15407/hftp14.02.249
9. Akman F., Kaçal M.R., Almousa N., Sayyed M.I., Polat H. Gamma-ray attenuation parameters for polymer composites reinforced with BaTiO3 and CaWO4 compounds. Prog Nucl Energy, 2020. 121, 103257. https://doi.org/10.1016/j.pnucene.2020.103257
10. Grygoruk V.І., Oliynyk V.V., Zagorodnii V.V., Lisachuk G.V., Kryvobok R.V., Zakharov A.V., Voloshchuk V.V., Maistat M.S. Microwave Electrodynamic Characteristics of Ceramic Materials. Journal of Nano- and Electronic Physics, 2022. 14(1), 01016-1-01016-4 https://doi.org/10.21272/jnep.14(1).01016
11. Lisachuk G. V., Sakhnenko N. D., Pitak Y. M., Krivobok R. V., Maystat M. S., Zakharov A. V., Voloschuk V. V., Saray V. V. Creation of electrically conductive composite ceramics based on facing tiles with the addition of SiC. Scientific Research on Refractories and Technical Ceramics, 2021. 121, 121-128. https://doi.org/10.35857/2663-3566.121.13
12. Lisachuk G., Krivobok R., Zakharov A., Voloschuk V., Maystat M., Sarai V. Technology of manufacture of radio absorption ceramics. Bulletin of the National Technical University "KhPI". Series: Innovation researches in students’ scientific work, 2021. 2(1362), 9-14. https://doi.org/10.20998/2220-4784.2021.02.02
13. Bhalla A., Guo R., Roy R. The perovskite structure – a review of its role in ceramic science and technology. Mat Res Innovat, 2000. 4, 3–26. https://link.springer.com/article/10.1007/s100190000062
14. Sun C., Zhou Y., Bai W., Xiao M., Feng K., Tong Y., Luo Z., Yang C. Study on the dielectric properties of SrTiO3 ceramics by CuO/Al2O3 insulation. Ceramics International, 2025. https://www.sciencedirect.com/science/article/abs/pii/S0272884225014075
15. Singh M., Yadav B. C., Ranjan A., Kaur, M., Gupta, S.K. Synthesis and characterization of perovskite barium titanate thin film and its application as LPG sensor. Sensors and Actuators B: Chemical, 2016. 241, 1170—1178 https://doi.org/10.1016/j.snb.2016.10.018
16. Lisachuk, G., Kryvobok, R., Zakharov, A., Voloshchuk, V., Maistat, M., Hlinskyi, D., Kolovorotnyi, B. (). Influence of the firing temperature on the dielectric properties of ceramics based on barium titanate. Technology Audit and Production Reserves, 2021. 5(3(61)), 10–13. https://doi.org/10.15587/2706-5448.2021.242865
17. Phoon B.L., Lai C.W., Juan J.C., Show P.‐L., Chen W.‐H. A review of synthesis and morphology of SrTiO3 for energy and other applications. Int J Energy Res, 2019. 43(10), 5151-5174 https://doi.org/10.1002/er.4505
18. Stanciu C., Hau S., Stanciu G., Tihon C. Er, Yb–codoped SrTiO3 ceramics: Synthesis, structural, microstructural and optical characterization. Ceramics International, 2025. 51(12(B)), 16771-16779. https://doi.org/10.1016/j.ceramint.2024.11.302
19. Zhong B., Zuo C., Yang C., Yang S., Li Y., Yu H., Wei X. Bifunctional europium doped SrTiO3 ceramics with energy storage and photoluminescence. Journal of Alloys and Compounds, 2022. 901, 163556. https://doi.org/10.1016/j.jallcom.2021.163556
20. Chung T.-H., Kwok K.W. Low-temperature-sintered Pr-doped 0.93(Bi0.5Na0.5)TiO3-0.07BaTiO3 multifunctional ceramics with Li2CO3 sintering aid. Journal of Alloys and Compounds, 2018. 737, 317-322. https://doi.org/10.1016/j.jallcom.2017.11.355
21. Lisachuk G., Kryvobok R., Pitak Y., Lapuzina O., Gusarova I., Lisachuk L., Grebenyuk A. Ceramics with adjustable dielectric properties based on the system SrO – TiO2 – SiO2. Przeglad Elektrotechniczny, 2018. 94(1), 163-166. https://doi.org/10.15199/48.2018.01.40
22. Benavente R., Salvador M.D., Centeno A., Alonso B., Zurutuza A., Borrell A. Study of Microwave Heating Effect in the Behaviour of Graphene as Second Phase in Ceramic Composites. Materials, 2020. 13(5), 1119. https://doi.org/10.3390/ma13051119
23. Dhawan S.K., Ohlan A., Singh K. Designing of Nano Composites of Conducting Polymers for EMI Shielding. Advances in Nanocomposites-Synthesis, Characterization and Industrial Applications, 2011. 429. https://doi.org/10.5772/14752